Terpinolene → Terpinen-4-ol

반응식

[O-]O.CC1CCC(=C(C)C)CC=1.[C:13]1([CH3:23])[CH2:18][CH2:17][C:16]([OH:22])([C:19]([CH3:21])=[CH2:20])[CH2:15][CH:14]=1>>[CH3:23][C:13]1[CH2:18][CH2:17][C:16]([OH:22])([CH:19]([CH3:20])[CH3:21])[CH2:15][CH:14]=1

참가 물질

반응물 3

HCID 11463Terpinolene

HCID 18500Perhydroxyl radical

HCID 527428Limonen-4-ol

생성물 1

HCID 11230Terpinen-4-ol

실험 절차

The hydroperoxide resulting from terpinolene can be reduced to p-mentha-1,8-dien-4-ol and this can be selectively catalytically hydrogenated to give 4-terpineol.

출처 및 근거

ORD 기록: ord-0e59f7fd459343bc9c88c2816f5b86b6
출처 데이터셋: uspto-grants-1997_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05620569

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