참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Styrene | HCID 7501 | — |
| 반응물 | Iodobenzene | HCID 11575 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 촉매 | Tetrabutylammonium Acetate | HCID 82707 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | Stilbene | HCID 11502 | 80% |
반응 단계
In a 60 ml miniautoclave, 85 mg of palladium in sol-gel matrix (cf. Example 71, metal content 0.1%) are suspended in 20 ml of DMF. After 2 mmol of iodobenzene, 2 mmol of styrene, and 4 mmol of tetrabutylammonium acetate have been added, heating at 60° C. is performed with shaking. After 12 h, 288 mg of stilbene can be isolated from the reaction solution. This corresponds to an 80% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05620584 |
|---|
| 출처 데이터셋 | uspto-grants-1997_04 |
|---|
| ORD ID | ord-16a1c44fd160492da55c51ef82c842aa |
|---|
| 출처 메모 | uspto-grants-1997_04 |
|---|
