Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2,6-Di-tert-butyl-4-(2-nitrostyryl)phenol → 4-(2-Aminophenethyl)-2,6-di-tert-butylphenol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2,6-Di-tert-butyl-4-(2-nitrostyryl)phenol | HCID 54141749 | — |
| 촉매 | HCID 178418390 | HCID 178418390 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 4-(2-Aminophenethyl)-2,6-di-tert-butylphenol | HCID 19960469 | 199.1% |
반응 단계
To a suspension of 2,6-di-tert-butyl-4-(2-nitrostyryl)phenol (16.4 g, 23.3 mmol) in ethanol (150 ml) was added a catalytic amount of 10% palladium carbon and the suspension was subjected to catalytic reduction at room temperature at 1-2.5 atms for 8 hrs and at 40° C. for 3 hrs. After filtering the catalyst, distilling off the solvent gave 4-(2-aminophenethyl)-2,6-di-tert-butylphenol (15.1 g, 100%) as a viscous oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05621010 |
| 출처 데이터셋 | uspto-grants-1997_04 |
| ORD ID | ord-7132e3607c4742b892cc59832a2db099 |
| 출처 메모 | uspto-grants-1997_04 |