Ethyl(4,7-dimethoxy-6-azaindol-3-yl)-oxoacetate → Potassium (4,7-dimethoxy-6-azaindol-3-yl)-oxoacetate
반응식
N1C2C(=CC=CN=2)C(C(=O)C([O-])=O)=C1.[K+:15].[CH3:16][O:17][C:18]1[CH:26]=[N:25][C:24]([O:27][CH3:28])=[C:23]2[C:19]=1[C:20]([C:29](=[O:35])[C:30]([O:32]CC)=[O:31])=[CH:21][NH:22]2>>[CH3:16][O:17][C:18]1[CH:26]=[N:25][C:24]([O:27][CH3:28])=[C:23]2[C:19]=1[C:20]([C:29](=[O:35])[C:30]([O-:32])=[O:31])=[CH:21][NH:22]2.[K+:15]참가 물질
3
실험 절차
Compound 3ao (Potassium (4,7-dimethoxy-6-azaindol-3-yl)-oxoacetate) was prepared (as a yellow solid), by the same method used to prepare compound 3a except Ethyl (4,7-dimethoxy-6-azaindol-3-yl)-oxoacetate was employed as the starting material. MS m/z: (M+H)+ of the corresponding acid of compound 3ao (M−K+H)+ calcd for C11H11N2O5: 251.07; found 251.09. HPLC retention time: 0.69 minutes (column B).
출처 및 근거
- ORD 기록
- ord-162474a13dbd46c1b7124b9c4de9260c
- 출처 데이터셋
- uspto-grants-2014_10