Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-Nitrophenyl methyl sulfide → 4-(Methylthio)aniline
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-Nitrophenyl methyl sulfide | HCID 96109 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 촉매 | Nickel | HCID 935 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | 4-(Methylthio)aniline | HCID 66038 | 92.7% |
반응 단계
A suspension of 1-(methylsulfanyl)-4-nitrobenzene (10.5 g, 0.062 mol) and Raney nickel (5 g) in methanol (250 ml) was hydrogenated in a round flask equipped with a balloon filled with hydrogen at room temperature for 16 hours. The resulting mixture was filtered and concentrated in vacuo to afford 8.0 g of 4-(methylsulfanyl)aniline as colorless oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08871756B2 |
| 출처 데이터셋 | uspto-grants-2014_10 |
| ORD ID | ord-2fca2c1116f94fabaf60c743e89bd88f |
| 출처 메모 | uspto-grants-2014_10 |