4-Phenyl-2-butanol → 4-Methoxybenzyl alcohol

HRID 541177

반응식

HRID 541177 반응식
O[CH:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6]N=1)[CH3:3].C1(CC[CH:18]([OH:20])C)C=CC=CC=1.C1C2C3[NH+]([O-:30])C(C2)CC1C3>>[CH3:18][O:20][C:4]1[CH:9]=[CH:8][C:7]([CH2:6][OH:30])=[CH:3][CH:2]=1

참가 물질

4

반응물 3

HCID 613024-Phenyl-2-butanolHCID 86784alpha-Methyl-2-pyridinemethanolHCID 1015366402-Oxido-2-azoniatricyclo[3.3.1.03,7]nonane

생성물 1

HCID 77384-Methoxybenzyl alcohol

실험 절차

2-(1-Hydroxyethyl)pyridine (76.8 mg, 0.624 mmol) was oxidized in the same manner as that described in Example 8, (a) (except that Nor-AZADO was used at 3 mol %, and the reaction was performed at room temperature) to obtain the objective compound (66.0 mg; yield, 87.4%). The spectrum data were found to be the same as those obtained in Example 6, (h).

후처리

  1. customwas performed at room temperature
  2. customto obtain
  3. customthe objective compound (66.0 mg; yield, 87.4%)

출처 및 근거

ORD 기록
ord-31220d8df9174332927d5f16647c901d
출처 데이터셋
uspto-grants-2014_10
특허 번호
US08871981B2

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