Sodium Bicarbonate → HCID 13931210, 화합물

HRID 543074노트

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HRID 543074 반응식
[Cl-].[CH3:2][O:3][C:4]1[CH:5]=[CH:6][C:7]2[Te:11][CH:10]([CH3:12])[NH2+:9][C:8]=2[CH:13]=1.C(=O)(O)[O-].[Na+]>O>[CH3:2][O:3][C:4]1[CH:5]=[CH:6][C:7]2[Te:11][C:10]([CH3:12])=[N:9][C:8]=2[CH:13]=1

참가 물질

4

반응물 2

HCID 516892Sodium BicarbonateHCID 198452855-Methoxy-2-methyl-3H-benzotellurazolium Chloride

생성물 1

HCID 13931210HCID 13931210, 화합물수율 97%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

5-Methoxy-2-methylbenzotellurazolium chloride (Example 13) (3.7 g=0.012 mole) was suspended in water, sodium bicarbonate in excess of that stoichiometrically required was added, and the free base product was extracted with diethyl ether. After washing with saturated sodium sulfate solution, the organic phase was dried and evaporated under reduced pressure to give a residual oil (3.2 g) which was identified by its nuclear magnetic resonance spectra. C, H, N, O and Te elemental analyses were in agreement with that expected for the structural formula.

후처리

  1. extractionthe free base product was extracted with diethyl ether
  2. washAfter washing with saturated sodium sulfate solution
  3. customthe organic phase was dried
  4. customevaporated under reduced pressure

출처 및 근거

ORD 기록
ord-0bb536069f944902a768dcd822791584
출처 데이터셋
uspto-grants-1987_04
특허 번호
US04661438

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