2-Propen-1-yl 1,1,1-trifluoromethanesulfonate → 2,5,6-Trimethyl-3-(2-propen-1-yl)benzotellurazolium Trifluoromethanesulfonate

HRID 543087노트

반응식

HRID 543087 반응식
[CH3:1][C:2]1[Te:3][C:4]2[CH:10]=[C:9]([CH3:11])[C:8]([CH3:12])=[CH:7][C:5]=2[N:6]=1.[F:13][C:14]([F:23])([F:22])[S:15]([O:18][CH2:19][CH:20]=[CH2:21])(=[O:17])=[O:16]>ClCCl>[F:13][C:14]([F:23])([F:22])[S:15]([O-:18])(=[O:17])=[O:16].[CH3:1][C:2]1[Te:3][C:4]2[CH:10]=[C:9]([CH3:11])[C:8]([CH3:12])=[CH:7][C:5]=2[N+:6]=1[CH2:21][CH:20]=[CH2:19]

참가 물질

4

반응물 2

HCID 109322232-Propen-1-yl 1,1,1-trifluoromethanesulfonateHCID 139312142,5,6-Trimethylbenzotellurazole

생성물 1

HCID 143241452,5,6-Trimethyl-3-(2-propen-1-yl)benzotellurazolium Trifluoromethanesulfonate

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

To a solution of 2,5,6-trimethylbenzotellurazole (Example 22) (9.90 g, 0.0033 mole) in dichloromethane (30 ml) was added the solution of 2-propen-1-yl trifluoromethanesulfonate (0.004 mole) rapidly at room temperature under a nitrogen atmosphere, with good stirring. Solid began separating 10 minutes after the addition was complete. Stirring under a nitrogen atmosphere was continued for about 18 hours. The solid was isolated by filtration, washed with diethyl ether, and dried under vacuum at room temperature. Yield 1.0 g, m.p. 162°-164° C. The mass spectra agreed with the assigned structural formula.

후처리

  1. customSolid began separating 10 minutes
  2. additionafter the addition
  3. customThe solid was isolated by filtration
  4. washwashed with diethyl ether
  5. customdried under vacuum at room temperature

출처 및 근거

ORD 기록
ord-1f368f6cdab64480a5779d251a1eee17
출처 데이터셋
uspto-grants-1987_04
특허 번호
US04661438

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