2',4'-Dihydroxyacetophenone → HCID 21294069, 화합물

HRID 543227노트

반응식

HRID 543227 반응식
Br[CH:2]([CH2:11][CH2:12][CH3:13])[CH2:3][CH2:4][CH2:5][CH2:6][C:7]([O:9]C)=[O:8].[CH3:14][C:15]([C:17]1[CH:18]=[CH:19][C:20]([OH:24])=[CH:21][C:22]=1[OH:23])=[O:16]>C(C(C)=O)C>[C:15]([C:17]1[CH:18]=[CH:19][C:20]([O:24][CH:2]([CH2:11][CH2:12][CH3:13])[CH2:3][CH2:4][CH2:5][CH2:6][C:7]([OH:9])=[O:8])=[CH:21][C:22]=1[OH:23])(=[O:16])[CH3:14]

참가 물질

4

반응물 2

HCID 69902',4'-DihydroxyacetophenoneHCID 21294048HCID 21294048, 화합물

생성물 1

HCID 21294069HCID 21294069, 화합물

시약·촉매·용매 1

HCID 6569Methyl Ethyl Ketone용매

실험 절차

Following the procedure of Example 48, 1.13 g. of methyl 6-bromo-nonanoate and 1.31 g. of 2,4-dihydroxyacetophenone were reacted in 50 ml. of methyl ethyl ketone. Hydrolysis of the resulting methyl ester intermediate gave 0.3 g. of the title product, M+ =308; NMR, IR.

후처리

  1. customgave 0.3 g

출처 및 근거

ORD 기록
ord-a31493ddec4144528b8cda4c56446404
출처 데이터셋
uspto-grants-1987_04
특허 번호
US04661505

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