2-Propenoic acid, 3-hydroxypropyl ester → Isopropenylphosphonic Acid Hydroxypropylacrylate

HRID 543453

반응식

HRID 543453 반응식
[OH:1][CH2:2][CH2:3][CH2:4][O:5][C:6](=[O:9])[CH:7]=[CH2:8].[C:10]([P:13](=[O:16])([OH:15])[OH:14])([CH3:12])=[CH2:11].S(OOS([O-])(=O)=O)([O-])(=O)=O.[NH4+].[NH4+]>O>[C:10]([P:13](=[O:14])([OH:16])[OH:15])([CH3:12])=[CH2:11].[OH:1][CH2:2][CH2:3][CH2:4][O:5][C:6](=[O:9])[CH:7]=[CH2:8]

참가 물질

5

반응물 3

HCID 331012-Propenoic acid, 3-hydroxypropyl esterHCID 62648Ammonium PersulfateHCID 557541Isopropenylphosphonic acid

생성물 1

HCID 86739384Isopropenylphosphonic Acid Hydroxypropylacrylate

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Using the same polymerization apparatus as described in Example 1, 17.1 g (0.13 mole) of hydroxypropylacrylate and 49.8 g (0.41 mole) of isopropenylphosphonic acid in 202.5 g water (neutralized to pH 2.5) was heated to reflux with 6 g of ammonium persulfate. After 2 hours of reflux an additional 6 g of initiator was added followed by 2 hours of reflux. The final pH of the brown solution was 2.7. The 31PMR spectrum of the product had polymer absorptions at -30 to -33 ppm and -24 ppm.

후처리

  1. temperaturewas heated
  2. additionwas added
  3. temperatureof reflux

출처 및 근거

ORD 기록
ord-8c1ecea281314f9e9e5dd0b7b0eafb75
출처 데이터셋
uspto-grants-1984_05
특허 번호
US04446028

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