Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ammonium → Isopropenyl Phosphonic Acid Hydroxypropylacrylate Methyl Acrylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ammonium | HCID 223 | — |
| 반응물 | Methyl Acrylate | HCID 7294 | — |
| 반응물 | 2-Propenoic acid, 3-hydroxypropyl ester | HCID 33101 | — |
| 반응물 | Isopropenylphosphonic acid | HCID 557541 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Isopropenyl Phosphonic Acid Hydroxypropylacrylate Methyl Acrylate | HCID 86739388 | — |
반응 단계
Aqueous isopropenyl phosphonic acid (71 g, 54%, 0.3 mole), hydroxypropylacrylate (13 g, 0.1 mole) and methyl acrylate (5 g, 0.06 mole) were mixed with 121.6 g water containing 6 g of ammonium pursulfate. After sparging with nitrogen for 1/2 hour, the mixture was heated to reflux for 11/2 hours. An additional 6 g of initiator was added followed by an equivalent period of reflux. The final product had a pH of 0.65. The 31PMR showed significant polymeric absorptions at -32.4 and -24.3 ppm.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04446028 |
| 출처 데이터셋 | uspto-grants-1984_05 |
| ORD ID | ord-7fa10ca3bcd24269b6131511e212eec6 |
| 출처 메모 | uspto-grants-1984_05 |