Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,3-Cyclohexanedione → 2-[[2-[4-(4-Trifluoromethylphenoxy)phenoxy]propionyl]]cyclohexane-1,3-dione
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,3-Cyclohexanedione | HCID 10434 | — |
| 반응물 | Thallium | HCID 5359464 | — |
| 반응물 | 2-{4-[4-(Trifluoromethyl)phenoxy]phenoxy}propanoyl fluoride | HCID 53941460 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 2-[[2-[4-(4-Trifluoromethylphenoxy)phenoxy]propionyl]]cyclohexane-1,3-dione | HCID 13364895 | — |
반응 단계
2-[4-(4-Trifluoromethylphenoxy)phenoxy]propionic acid fluoride (0.10 mol) is added to a solution of the thallium salt of cyclohexane-1,3-dione in ether (200 ml) over a period of 30 minutes. The mixture is filtered and the filtrate is concentrated to give 2-[[2-[4-(4-trifluoromethylphenoxy)phenoxy]propionyl]]cyclohexane-1,3-dione (V; Y is H, Z is CF3, R1 is CH3 and n is two).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04448965 |
| 출처 데이터셋 | uspto-grants-1984_05 |
| ORD ID | ord-2fab2acdd5704cbd93a970619e0cc355 |
| 출처 메모 | uspto-grants-1984_05 |