Cyclobutane-1,3-dione → 2-[[2-[4-(4-Trifluoromethylphenoxy)phenoxy]propionyl]]cyclobutane-1,3-dione

HRID 544192

반응식

HRID 544192 반응식
[F:1][C:2]([F:23])([F:22])[C:3]1[CH:21]=[CH:20][C:6]([O:7][C:8]2[CH:19]=[CH:18][C:11]([O:12][CH:13]([CH3:17])[C:14](F)=[O:15])=[CH:10][CH:9]=2)=[CH:5][CH:4]=1.[Tl].[C:25]1(=[O:30])[CH2:28][C:27](=[O:29])[CH2:26]1>>[F:1][C:2]([F:23])([F:22])[C:3]1[CH:21]=[CH:20][C:6]([O:7][C:8]2[CH:19]=[CH:18][C:11]([O:12][CH:13]([CH3:17])[C:14]([CH:26]3[C:27](=[O:29])[CH2:28][C:25]3=[O:30])=[O:15])=[CH:10][CH:9]=2)=[CH:5][CH:4]=1

참가 물질

4

반응물 3

HCID 27357Cyclobutane-1,3-dioneHCID 5359464ThalliumHCID 539414602-{4-[4-(Trifluoromethyl)phenoxy]phenoxy}propanoyl fluoride

생성물 1

HCID 204271862-[[2-[4-(4-Trifluoromethylphenoxy)phenoxy]propionyl]]cyclobutane-1,3-dione

실험 절차

In the same manner, 2-[4-(4-trifluoromethylphenoxy)phenoxy]propionic acid fluoride is reacted with the thallium salt of cyclobutane-1,3-dione to yield 2-[[2-[4-(4-trifluoromethylphenoxy)phenoxy]propionyl]]cyclobutane-1,3-dione (V; Y is H, Z is CF3, R1 is CH3 and n is zero).

출처 및 근거

ORD 기록
ord-1d6ec8641aee45d7a517e581ba91c78a
출처 데이터셋
uspto-grants-1984_05
특허 번호
US04448965

연결된 노트

불러오는 중…