2-Oxazolidinone → 3-(4-Tert.-butylphenylthio)-oxazolidin-2-one

반응식

[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11]Cl)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[O:13]1[CH2:17][CH2:16][NH:15][C:14]1=[O:18]>>[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11][N:15]2[CH2:16][CH2:17][O:13][C:14]2=[O:18])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]

참가 물질

반응물 2

HCID 739492-Oxazolidinone

HCID 12801136p-t-Butylbenzenesulfenyl chloride

생성물 1

HCID 130968073-(4-Tert.-butylphenylthio)-oxazolidin-2-one

실험 절차

Analogously to Example 4, 2.7 g of 3-(4-tert.-butylphenylthio)-oxazolidin-2-one were obtained as colourless crystals with a melting point of 76° to 81° C. from 4-tert.-butylphenylsulphenyl chloride and oxazolidin-2-one.

출처 및 근거

ORD 기록: ord-f819118ee5704277a5b947e4cb90acb3
출처 데이터셋: uspto-grants-1984_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04451475

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