4-Cyanophenylvinyl cyclopropyl ketone → HCID 13316970, 화합물
반응식
[CH:1]1([C:4]([CH:6]=[CH:7][C:8]2[CH:13]=[CH:12][C:11]([C:14]#[N:15])=[CH:10][CH:9]=2)=[O:5])[CH2:3][CH2:2]1>C(O)C.[Pd]>[CH:1]1([C:4]([CH2:6][CH2:7][C:8]2[CH:9]=[CH:10][C:11]([C:14]#[N:15])=[CH:12][CH:13]=2)=[O:5])[CH2:3][CH2:2]1참가 물질
4
실험 절차
A solution of 11.83 g of 4-cyanophenylvinyl cyclopropyl ketone in 200 ml of absolute ethanol containing 0.3 g of 10% palladium-on-carbon catalyst was hydrogenated at an initial pressure of 45 pounds per sq. in. for one hour. The catalyst was filtered off, and the product isolated from the filtrate and recrystallized from methanol to give 8.9 g of 4-cyanophenylethyl cyclopropyl ketone, m.p. 76° C.
후처리
- filtrationThe catalyst was filtered off
- customthe product isolated from the filtrate
- customrecrystallized from methanol
출처 및 근거
- ORD 기록
- ord-61d5cd5b431f4e3490a8a7126b0829d3
- 출처 데이터셋
- uspto-grants-1984_05
- 특허 번호
- US04451476
반응 노트
불러오는 중…