Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2,4,6-Trinitrotoluene → 2-Amino-4,6-Dinitrotoluene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2,4,6-Trinitrotoluene | HCID 8376 | — |
| 촉매 | Iron | HCID 23925 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 2-Amino-4,6-Dinitrotoluene | HCID 37182 | 43.8% |
반응 단계
1.0 gram of 2,4,6-trinitrotoluene was dissolved in 22 ml of glacial acetic acid. With vigorous stirring, 0.82 g of iron powder (400 mesh) was added in small portions over two hours. The red reaction suspension was diluted to 50 ml with water giving a bright yellow precipitate. Filtration gave 0.38 grams of 2-amino-4,6-dinitrotoluene of sufficient spectral and chromatographic purity for use in the subsequent synthesis without recrystallization.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04451681 |
| 출처 데이터셋 | uspto-grants-1984_05 |
| ORD ID | ord-974e83d93d874cd9840231258ba95000 |
| 출처 메모 | uspto-grants-1984_05 |