Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → Dimethyl-bis(2-methyl-1H-inden-1-yl)silane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Dichlorodimethylsilane | HCID 6398 | — |
| 반응물 | 1H-Indene, 2-methyl- | HCID 16587 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 용매 | Hexane | HCID 8058 | — |
| 용매 | Butyllithium | HCID 178418339 | — |
| 생성물 | Dimethyl-bis(2-methyl-1H-inden-1-yl)silane | HCID 4050248 | 68% |
반응 단계
In a 500 ml glass reactor, 4.3 g (33 mmole) of 2-methylindene was dissolved in 80 ml of tetrahydrofuran, to which 21 ml of 1.6M n-butyllithium in hexane was slowly added under cooling. After the mixture was stirred at room tempearture for 1 hour, it was cooled again, and 2.1 g of dimethyldichlorosilane was added dropwise. After the mixture was stirred at room temperature for 12 hours, 50 ml of water was added, and the organic phase was separated and dried to give 3.5 g of dimethylbis(2-methylindenyl)silane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05623022 |
| 출처 데이터셋 | uspto-grants-1997_04 |
| ORD ID | ord-151018c2ea9f40899b919dffed3610ca |
| 출처 메모 | uspto-grants-1997_04 |