N-benzyl-1-phenylethylamine → N-benzyl-1-phenylethanimine

HRID 546329노트

반응식

HRID 546329 반응식
[CH2:1]([NH:8][CH:9]([C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[CH3:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.N1C=CC=CC=1.C(OC(=O)C)(=O)C>>[C:11]1([C:9](=[N:8][CH2:1][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH3:10])[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1

참가 물질

3

반응물 2

HCID 519427N-benzyl-1-phenylethylamineHCID 22348678Acetic anhydride pyridine

생성물 1

HCID 297338N-benzyl-1-phenylethanimine

실험 절차

Benzyl-(1-phenylethyl)amine, conversion>99%, ee 82% (GC, sample derivatised by treatment with acetic anhydride pyridine, Chirasil DEX CB, 25 m×0.25 mm, injector/detector 200° C., helium 20 psi, 170° C. for 40 minutes then ramp at 15° C./min to 200° C., retention times 29.71 minutes and 30.73 minutes).

후처리

  1. customthen ramp at 15° C./min to 200° C., retention times 29.71 minutes and 30.73 minutes

출처 및 근거

ORD 기록
ord-13ba5d3ba5294e9b950de64a67b4ef6c
출처 데이터셋
uspto-grants-2011_05
특허 번호
US07935841B2

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