Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → Ethanethioic acid cis-(+/-)-S-[5-[[(aminocarbonyl)oxy]methyl]tetrahydro-3-furanyl]ester
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Trichloroacetyl isocyanate | HCID 76400 | — |
| 반응물 | Ethanethioic acid cis (+/-)-S-[tetrahydro-5-(hydroxymethyl)-3-furanyl]ester | HCID 86750314 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 용매 | Tetrabutylammonium Fluoride | HCID 2724141 | — |
| 생성물 | Ethanethioic acid cis-(+/-)-S-[5-[[(aminocarbonyl)oxy]methyl]tetrahydro-3-furanyl]ester | HCID 86750313 | — |
반응 단계
The title compound is prepared by the procedure of Example 7 using 0.28 g of product from Example 9 in 20 ml of methylene chloride, 0.208 ml of trichloroacetyl isocyanate, 0.80 ml of acetic acid, 6.79 ml of 1M tetrabutylammonium fluoride in tetrahydrofuran and 0.37 ml of water to give 0.320 g of the desired product.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05623081 |
| 출처 데이터셋 | uspto-grants-1997_04 |
| ORD ID | ord-5ce210a07f8045098a967abf4013a763 |
| 출처 메모 | uspto-grants-1997_04 |