4-Methoxyphenol → Urethane acrylate

HRID 547877노트

반응식

HRID 547877 반응식
[CH2:1]([OH:23])[CH2:2][CH2:3]CCCCCCCCCCCCCCCCCCC.C(N=C=O)CCCCCN=C=[O:32].C1C=C(C[N:43]=[C:44]=[O:45])C=C(CN=C=O)C=1.C([O-])(=O)CCCCCCCCCCC.C([Sn+2]CCCC)CCC.C([O-])(=O)CCCCCCCCCCC.C(OCCO)(=O)C=C.COC1C=CC(O)=CC=1>C1(C)C=CC=CC=1>[C:1]([OH:23])(=[O:32])[CH:2]=[CH2:3].[NH2:43][C:44]([O:23][CH2:1][CH3:2])=[O:45]

참가 물질

8

반응물 6

HCID 90154-MethoxyphenolHCID 12620Behenyl Alcohol2회HCID 131652-Hydroxyethyl acrylateHCID 13192Hexamethylene diisocyanateHCID 192621,3-Bis(isocyanatomethyl)benzeneHCID 9809426Di-n-butyldilauryltin2회

생성물 1

HCID 21863578Urethane acrylate

시약·촉매·용매 1

HCID 1140Toluene용매2회

반응 조건

온도
40 °C

실험 절차

Into 50 parts of toluene, 5.8 parts of behenyl alcohol (“NAA-422”, trade name, produced by NOF Corporation, hydroxyl value: 180) was added and the mixture was heated up to 40° C. After thorough dissolution of the behenyl alcohol, 50 parts of hexamethylene diisocyanate subjected to isocyanurate modification (“TAKENATE D-170N”) was added and the mixture was maintained at 70° C. for 30 minutes. Subsequently, 0.02 parts of dibutyltin laurate was added and the mixture was maintained at 70° C. for 3 hours. Further, 2.8 parts of 2-hydroxyethyl acrylate (Light Ester HOA), 36.1 parts of polycaprolactone-modified hydroxyethyl acrylate (“PLACCEL FA1”), 48.1 parts of polycaprolactone-modified hydroxyethyl acrylate (“PLACCEL FA5”), 0.02 parts of dibutyltin laurate and 0.02 parts of hydroquinone monomethyl ether were added and the mixture was maintained at 70° C. for 5 hours. Thereafter, 92.8 parts of toluene was added to obtain a urethane acrylate having a solid content of 50% by weight. The average number of repetitions per one molecule of the urethane acrylate relative to the number of repetitions of a caprolactone unit per one residue of an acrylate monomer is 2. Further, the maximum difference in the number of repetitions between two kinds of the urethane acrylates is 5.

후처리

  1. additionwas added
  2. temperaturethe mixture was maintained at 70° C. for 30 minutes
  3. temperaturethe mixture was maintained at 70° C. for 3 hours
  4. temperaturethe mixture was maintained at 70° C. for 5 hours

출처 및 근거

ORD 기록
ord-322ffd5ad37a4837bd6265a5574f150c
출처 데이터셋
uspto-grants-2011_05
특허 번호
US07939608B2

반응 노트

불러오는 중…