Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triethylamine → 3-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]thio]-N,N-dicyclohexylpropanamide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | 2,6-Di-tert-butyl-4-mercaptophenol | HCID 70370 | — |
| 반응물 | 2-Propenamide, N,N-dicyclohexyl- | HCID 10105498 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | 3-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]thio]-N,N-dicyclohexylpropanamide | HCID 9826140 | — |
반응 단계
The title compound of Example 3 (1.9 g, 0.008 mole), 2,6-bis(1,1-dimethylethyl)-4-mercaptophenol(2 g, 0.008 mole) and triethylamine (0.5 ml) were stirred in methanol (25 ml) for about 12 hours. The solvent was removed in vacuo on a rotary evaporator, the crude material purified by chromatography on silica and recrystallized from hexane, m.p. ca. 168.5°-172° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05244899 |
| 출처 데이터셋 | uspto-grants-1993_09 |
| ORD ID | ord-83a7fad34b684fd8a233fc5ded25c4c5 |
| 출처 메모 | uspto-grants-1993_09 |