Acetic Acid → HCID 67151037, 화합물

HRID 549475노트

반응식

HRID 549475 반응식
[Cl:1][C:2]1[CH:3]=[CH:4][C:5]2[CH:6]=CC3[C:13]([C:14]=2[CH:15]=1)=[CH:12][CH:11]=[CH:10][CH:9]=3.[OH2:16].[C:17]([OH:20])(=O)[CH3:18]>>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]2[C:6](=[O:16])[C:17](=[O:20])[C:18]3[C:13]([C:14]=2[CH:15]=1)=[CH:12][CH:11]=[CH:10][CH:9]=3

참가 물질

4

반응물 3

HCID 176Acetic AcidHCID 962WaterHCID 3013936Phenanthrene, 3-chloro-

생성물 1

HCID 67151037HCID 67151037, 화합물수율 88%

반응 조건

온도
100 °C

실험 절차

To a solution of 12.5 g (58.7 mmol) of 3-chlorophenanthrene from Step 3 in 350 mL of acetic acid was added 23.5 g (0.23 mol) of CrO3. The reaction was stirred 2 hrs at 100° C., cooled down to room temperature and poured into 2 L of water. The suspension was stirred 1 hr, filtered and washed with water. The residue was dried under high vacuum to afford 12.5 g (88%) of 3-chlorophenanthrene-9,10-dione.

후처리

  1. temperaturecooled down to room temperature
  2. stirringThe suspension was stirred 1 hr
  3. filtrationfiltered
  4. washwashed with water
  5. customThe residue was dried under high vacuum

출처 및 근거

ORD 기록
ord-8f0f3a16940245d3bbef260c166d2416
출처 데이터셋
uspto-grants-2011_05
특허 번호
US07943649B2

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