(R)-1,2-Epoxypropane → (R)-oct-7-en-2-ol

반응식

[O:1]1[C@H:3]([CH3:4])[CH2:2]1.[CH2:5]([Mg]Br)[CH2:6][CH2:7][CH:8]=[CH2:9]>>[CH3:4][C@@H:3]([OH:1])[CH2:2][CH2:9][CH2:8][CH2:7][CH:6]=[CH2:5]

참가 물질

반응물 2

HCID 146261(R)-1,2-Epoxypropane

HCID 178445862HCID 178445862, 화합물

생성물 1

HCID 11240489(R)-oct-7-en-2-ol

실험 절차

As shown in the reaction formula 2, the (R)-(+)-1,2-epoxypropane is added to separately synthesized 1M 4-pentenyl magnesium bromide, obtaining a (2R)-7-octen-2-ol (III).

출처 및 근거

ORD 기록: ord-8ab75dc722514d229e5e91f6a8467efa
출처 데이터셋: uspto-grants-2011_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07951839B2

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