m-Chloroperbenzoic acid → HCID 178508075, 화합물

HRID 555221

반응식

HRID 555221 반응식
[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N:3]=1.ClC1C=CC=C(C(OO)=[O:19])C=1>CC(C)=O>[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N+:3]=1[O-:19]

참가 물질

4

반응물 2

HCID 70297m-Chloroperbenzoic acidHCID 778873-Nitropyridin-2-ylamine

생성물 1

HCID 178508075HCID 178508075, 화합물

시약·촉매·용매 1

HCID 180Acetone용매3회

실험 절차

To a solution of 2-amino-3-nitropyridine (5.0 g; 36 mmol) in acetone (250 mL) was added a solution of m-chloroperbenzoic acid (7.5 g; 100 mmol) in acetone (50 mL). The shiny orange solution was stirred at room temperature for 3 days. The resulting precipitate was dissolved again under heating and the solution poured onto a silica gel column. Column chromatography using acetone as eluant gave the title compound as an orange solid.

후처리

  1. dissolutionThe resulting precipitate was dissolved again
  2. temperatureunder heating
  3. additionthe solution poured onto a silica gel column

출처 및 근거

ORD 기록
ord-f7313a66e43d401fa561836b9a73d649
출처 데이터셋
uspto-grants-2011_11
특허 번호
US08053212B1

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