(Phenylmethyl)hydrazine → HCID 46193502, 화합물

HRID 555651노트

반응식

HRID 555651 반응식
[Se:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]([C:8]1[CH:13]=[CH:12][C:11]([C:14]([O:16][CH3:17])=[O:15])=[CH:10][CH:9]=1)=O.[CH2:18]([NH:25][NH2:26])[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1.C(N1C2C=C[Se]C=2C(C2OC(C(OC)=O)=CC=2)=N1)C1C=CC=CC=1>C(O)(=O)C>[CH2:18]([N:25]1[C:3]2[CH:4]=[CH:5][Se:1][C:2]=2[C:6]([C:8]2[CH:13]=[CH:12][C:11]([C:14]([O:16][CH3:17])=[O:15])=[CH:10][CH:9]=2)=[N:26]1)[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1

참가 물질

5

반응물 3

HCID 11157(Phenylmethyl)hydrazineHCID 46193254p-Methoxycarbonylphenyl 2-selenophenyl ketoneHCID 46193500HCID 46193500, 화합물

생성물 1

HCID 46193502HCID 46193502, 화합물

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

Compound 63 (5.86 g, 0.02 mole), benzylhydrazine 50 (4.88 g, 0.04 mole) and glacial acetic acid (1.5 ml) were allowed to react as in the preparation of compound 55 to afford compound 67. Yield: 2.49 g (31.4%); white crystals; mp 150-153° C.

출처 및 근거

ORD 기록
ord-4156d3071a3343a18d49e066173fd7b5
출처 데이터셋
uspto-grants-2011_11
특허 번호
US08053459B1

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