Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium methanolate methanol → 3-Bromo-2-methoxy-6-methyl-pyridine 1-oxide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium methanolate methanol | HCID 23694274 | — |
| 반응물 | 3-Bromo-2-chloro-6-methylpyridin-1-ium-1-olate | HCID 85706489 | — |
| 생성물 | 3-Bromo-2-methoxy-6-methyl-pyridine 1-oxide | HCID 67001239 | — |
반응 단계
step b—A solution of 52a (0.5 g) and 0.5 M NaOMe/MeOH (4.9 mL) was stirred at RT overnight. The reaction mixture was concentrated in vacuo and the residue loaded on a SiO2 column and eluted with 5% MeOH/DCM to afford 3-bromo-2-methoxy-6-methyl-pyridine 1-oxide (52b).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08063072B2 |
| 출처 데이터셋 | uspto-grants-2011_11 |
| ORD ID | ord-f15a14dd19e84090bd4768590ff4b7f6 |
| 출처 메모 | uspto-grants-2011_11 |