Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
N-Benzylideneaniline → N-Methylbenzylamine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | N-Benzylideneaniline | HCID 10858 | — |
| 반응물 | Ethenamine, 2-phenyl- | HCID 155076 | — |
| 촉매 | Cobalt | HCID 104730 | — |
| 생성물 | N-Methylbenzylamine | HCID 7669 | — |
| 생성물 | Benzylaniline | HCID 66028 | — |
반응 단계
Imines were hydrogenated using in situ-generated complex 2. Hydrogenation of N-benzylidene benzylamine proceeded under 4 atm H2 at 60° C. to afford dibenzylamine in 84% isolated yield using 2 mol % of complex 2 (Table 2, entry 13). N-Benzylidenemethylamine and N-benzylideneaniline were also hydrogenated by the cobalt catalyst, affording N-benzyl methyl amine and N-benzylaniline in good yields (Table 2, entries 14 and 15). Previous examples of cobalt-catalyzed imine hydrogenation are scarce.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09434666B2 |
| 출처 데이터셋 | uspto-grants-2016_09 |
| ORD ID | ord-4a4db7e6614b4d4ab660ea8ce57cdbad |
| 출처 메모 | uspto-grants-2016_09 |