N,N,3-trimethyl-4-nitrobenzamide → 4-amino-N,N,3-trimethylbenzamide

HRID 562508

반응식

HRID 562508 반응식
[CH3:1][N:2]([CH3:15])[C:3](=[O:14])[C:4]1[CH:9]=[CH:8][C:7]([N+:10]([O-])=O)=[C:6]([CH3:13])[CH:5]=1>CO>[NH2:10][C:7]1[CH:8]=[CH:9][C:4]([C:3]([N:2]([CH3:15])[CH3:1])=[O:14])=[CH:5][C:6]=1[CH3:13]

참가 물질

3

반응물 1

HCID 786992N,N,3-trimethyl-4-nitrobenzamide

생성물 1

HCID 167817704-amino-N,N,3-trimethylbenzamide

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

N,N,3-trimethyl-4-nitrobenzamide (0.6 g, 2.88 mmol) in methanol was hydrogenated using the H-cube apparatus (1.2 mL/min, RT, atmospheric pressure). After 45 minutes the reaction was complete. Removal of the solvent in vacuo gave 4-amino-N,N,3-trimethylbenzamide as a colourless solid (quantitative); MS (ES+) 179.

후처리

  1. customthe H-cube apparatus (1.2 mL/min, RT, atmospheric pressure)
  2. customRemoval of the solvent in vacuo

출처 및 근거

ORD 기록
ord-d22c9a6b44974ca3aff721ada566f115
출처 데이터셋
uspto-grants-2011_11
특허 번호
US08067417B2

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