Geraniol → 3,7-Dimethyl-1-octanol

HRID 5629

반응식

HRID 5629 반응식
[CH3:1][C:2](=[CH:4][CH2:5][CH2:6]/[C:7](=[CH:9]/[CH2:10][OH:11])/[CH3:8])[CH3:3]>C(O)C.[Pt]=O>[CH3:8][CH:7]([CH2:6][CH2:5][CH2:4][CH:2]([CH3:3])[CH3:1])[CH2:9][CH2:10][OH:11]

참가 물질

4

반응물 1

HCID 637566Geraniol

생성물 1

HCID 77923,7-Dimethyl-1-octanol수율 97.5%

시약·촉매·용매 2

HCID 82844Platinum oxide (PtO)촉매HCID 702Ethanol용매

실험 절차

Geraniol (100 g) was dissolved in ethanol (500 ml), added with platinum oxide (500 mg) and stirred for 24 hours at room temperature under hydrogen atmosphere. After the completion of the reaction, insoluble material was removed by filtration through a Celite layer and the filtrate was concentrated under reduced pressure to obtain 3,7-dimethyloctanol (100 g).

후처리

  1. customAfter the completion of the reaction, insoluble material
  2. customwas removed by filtration through a Celite layer
  3. concentrationthe filtrate was concentrated under reduced pressure

출처 및 근거

ORD 기록
ord-c0dfd353e6324d3daf2c3d50805ae08b
출처 데이터셋
uspto-grants-1993_09
특허 번호
US05245070

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