Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-Dodecanol → Dodecyl(chlorosulfonyl)carbamate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-Dodecanol | HCID 8193 | — |
| 반응물 | Chlorosulfonyl isocyanate | HCID 70918 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Dodecyl(chlorosulfonyl)carbamate | HCID 10758631 | 101.6% |
반응 단계
A solution of n-dodecyl alcohol (10.7 g, 57.4 mmoles) in 100 mL Et2O was added dropwise to a solution of chlorosulfonyl isocyanate (5.0 mL, 57.4 mmoles) in 100 mL Et2O at ~15° C. under an atmosphere of N2. The resulting mixture was stirred for 2 hours and concentrated in vacuo. The residue was triturated with cold hexanes to give a white solid and collected by filtration to give 19.12 g of a white solid, mp 62°-63° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05245068 |
| 출처 데이터셋 | uspto-grants-1993_09 |
| ORD ID | ord-0b945865b6ed43e89b1d0e52682f9023 |
| 출처 메모 | uspto-grants-1993_09 |