Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Phenylprop-2-En-1-Ol → 3-Phenylprop-2-Enal
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Phenylprop-2-En-1-Ol | HCID 308 | — |
| 반응물 | Veratraldehyde | HCID 8419 | — |
| 반응물 | 1-Hydroxybenzotriazole | HCID 75771 | — |
| 반응물 | 6-benzothiazolesulfonic acid, 2,2'-azinobis(3-ethyl-2,3-dihydro-, diammonium salt | HCID 9570474 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 3-Phenylprop-2-Enal | HCID 307 | 48% |
반응 단계
213 mg (1.59 mmol) of 3-phenyl-2-propen-1-ol in 1.1 ml of ethanol were treated at 45° C. with stirring into 22 ml of buffer solution (see Example 1) with 24.3 mg (0.180 mmol) of 1-hydroxy-1H-benzotriazole. After approx. 10 minutes, 5 ml of an aqueous solution of 2 mg/ml laccase from Trametes versicolor (specific activity approx. 18 IU/mg, defined with ABTS as the substrate) were added. After 3 hours in contact with the air, 48% of 3-phenyl-2-propenal were formed (GC analysis), and a further 24.3 mg of HOBT and 5 ml of laccase solution were added. GC analysis after 6 hours revealed complete conversion into 3-phenyl-2-propenal.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06169213A |
| 출처 데이터셋 | uspto-grants-2001_01 |
| ORD ID | ord-d1bcdfe08e014a60849b73cee79e34d3 |
| 출처 메모 | uspto-grants-2001_01 |