Nitromethane → HCID 54347464, 화합물

HRID 569089노트

반응식

HRID 569089 반응식
[CH2:1]([O:3][C:4]([C:6]1[N:7]=[CH:8][C:9]2[NH:10][C:11]3[C:16]([C:17]=2[C:18]=1[CH3:19])=[C:15]([CH:20]=O)[CH:14]=[CH:13][CH:12]=3)=[O:5])[CH3:2].[N+:22]([CH3:25])([O-:24])=[O:23].Cl.CN.C(=O)([O-])[O-].[Na+].[Na+]>C(O)C>[CH2:1]([O:3][C:4]([C:6]1[N:7]=[CH:8][C:9]2[NH:10][C:11]3[C:16]([C:17]=2[C:18]=1[CH3:19])=[C:15]([CH:20]=[CH:25][N+:22]([O-:24])=[O:23])[CH:14]=[CH:13][CH:12]=3)=[O:5])[CH3:2]

참가 물질

6

반응물 4

HCID 6375NitromethaneHCID 10340Sodium CarbonateHCID 6364545Methylamine hydrochlorideHCID 54371401HCID 54371401, 화합물

생성물 1

HCID 54347464HCID 54347464, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

A solution of 5-formyl-4-methyl-beta-carboline-3-carboxylic acid ethyl ester (10 g), nitromethane (2 ml) and methylamine hydrochloride (0.2 g) in ethanol (50 ml) is mixed with sodium carbonate (0.3 g) and left for 5 days at 20° C. with occasional shaking. Then it is evaporated to beginning crystallization. 5 g of the title compound crystallizers from the solution cooled with ice water.

후처리

  1. customThen it is evaporated
  2. customcrystallization
  3. temperature5 g of the title compound crystallizers from the solution cooled with ice water

출처 및 근거

ORD 기록
ord-c742e44923574d4bb065a15fa09ccb60
출처 데이터셋
uspto-grants-1988_03
특허 번호
US04731365

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