Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Carbonate → 2-(Oxiran-2-yl)benzene-1-sulfonamide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 2-Ethenylbenzenesulfonamide | HCID 11367403 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | 2-(Oxiran-2-yl)benzene-1-sulfonamide | HCID 13884523 | — |
반응 단계
A solution consisting of 2-ethenylbenzenesulfonamide (1.5 g, 8.1 mmol) m-chloroperbenzoic acid (1.4 g, 8.1 mmol) and potassium carbonate (1.1 g, 8.1 mmol) in 150 ml of chloroform was stirred for 4 days at room temperature. The reaction was filtered and the filtrate was washed with saturated sodium bicarbonate. The organic layer was separated, dried and concentrated. The resulting oil was flash chromatographed (methylene chloride) to yield the subject compound as a white solid, m.p. 136°-139° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04732604 |
| 출처 데이터셋 | uspto-grants-1988_03 |
| ORD ID | ord-61218c3e69fa460da834ee153f38e71b |
| 출처 메모 | uspto-grants-1988_03 |