Hydrazine → HCID 178434195, 화합물

HRID 569892

반응식

HRID 569892 반응식
[C:1]([CH:4]1[C:9](=[O:10])[CH2:8][CH2:7][CH2:6][C:5]1=O)(=O)[CH3:2].[NH2:12][NH2:13]>CO>[CH3:2][C:1]1[C:4]2[C:9](=[O:10])[CH2:8][CH2:7][CH2:6][C:5]=2[NH:13][N:12]=1

참가 물질

4

반응물 2

HCID 9321HydrazineHCID 1381042-Acetyl-1,3-cyclohexanedione

생성물 1

HCID 178434195HCID 178434195, 화합물

시약·촉매·용매 1

HCID 887Methanol용매2회

실험 절차

To an ice-cold solution of 33.3 grams of 2-acetyl1,3-cyclohexanedione in 400 ml of methanol was added dropwise a solution of 7.2 ml of hydrazine in 50 ml of methanol and the resulting reaction mixture was heated at reflux for 20 hours. The solvent was then removed under reduced pressure and the residue was triturated in ethyl ether to give 1,5,6,7-tetrahydro-3-methyl-4H-indazol-4-one as a yellow crystalline solid melting at about 154°-157° C.

후처리

  1. customthe resulting reaction mixture
  2. temperaturewas heated
  3. temperatureat reflux for 20 hours
  4. customThe solvent was then removed under reduced pressure
  5. customthe residue was triturated in ethyl ether

출처 및 근거

ORD 기록
ord-ae23a9e5c6a941738e1d4046f760fa91
출처 데이터셋
uspto-grants-1988_03
특허 번호
US04734429

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