Selectfluor → HCID 10719166, 화합물

HRID 571431노트

반응식

HRID 571431 반응식
F[B-](F)(F)F.F[B-](F)(F)F.[Cl:11][CH2:12][N+:13]12[CH2:20][CH2:19][N+:16]([F:21])([CH2:17][CH2:18]1)[CH2:15][CH2:14]2.[F:22][P-:23]([F:28])([F:27])([F:26])([F:25])[F:24].[NH4+]>O>[F:22][P-:23]([F:28])([F:27])([F:26])([F:25])[F:24].[F:22][P-:23]([F:28])([F:27])([F:26])([F:25])[F:24].[Cl:11][CH2:12][N+:13]12[CH2:20][CH2:19][N+:16]([F:21])([CH2:17][CH2:18]1)[CH2:15][CH2:14]2

참가 물질

4

반응물 2

HCID 2724933SelectfluorHCID 9793912Ammonium hexafluorophosphate

생성물 1

HCID 10719166HCID 10719166, 화합물수율 101.3%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

To 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (1) (1.06 g, 3.00 mmol, 1.00 equiv) in H2O (9.0 mL) at 23° C. was added ammonium hexafluorophosphate (2.93 g, 18.0 mmol, 6.00 equiv). After stirring for 1 h, the suspension was filtered off and washed with H2O (5×5 mL) and Et2O (10 mL) to afford 1.43 g of the title compound as a colorless solid (quantitative yield).

후처리

  1. filtrationthe suspension was filtered off
  2. washwashed with H2O (5×5 mL) and Et2O (10 mL)

출처 및 근거

ORD 기록
ord-d665c7d3bfa1489f8c0a5210573d07a2
출처 데이터셋
uspto-grants-2015_05
특허 번호
US09024093B2

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