Trichloroethanol → 2,2,2-Trichloroethyl 5-(tetradecyloxy)furan-2-carboxylate

반응식

[CH2:1]([O:15][C:16]1[O:20][C:19]([C:21]([OH:23])=[O:22])=[CH:18][CH:17]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[Cl:24][C:25]([Cl:29])([Cl:28])[CH2:26]O>>[CH2:1]([O:15][C:16]1[O:20][C:19]([C:21]([O:23][CH2:26][C:25]([Cl:29])([Cl:28])[Cl:24])=[O:22])=[CH:18][CH:17]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

참가 물질

반응물 2

HCID 8259Trichloroethanol

HCID 1151755-(Tetradecyloxy)-2-furoic acid

생성물 1

HCID 498698982,2,2-Trichloroethyl 5-(tetradecyloxy)furan-2-carboxylate

실험 절차

The title compound was prepared as described in Example 1 starting from 0.228 g (0.7 mmol) of 5-(tetradecyloxy)furan-2-carboxylic acid and 0.196 mL (2.04 mmol) of 2,2,2-trichloroethanol. 1H NMR (400 MHz, DMSO-d6) δ: 7.4 (d, 1H), 5.74 (d, 1H), 5.03 (s, 2H), 4.19 (t, 2H), 1.7 (p, 2H), 1.2-1.5 (m, 22H), 0.85 (t, 3H).

출처 및 근거

ORD 기록: ord-9db678fdae484c24a8e2fa052365a9ff
출처 데이터셋: uspto-grants-2016_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09434718B2

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