Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Bromoethanol → 2-Bromoethyl 5-(tetradecyloxy)furan-2-carboxylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Bromoethanol | HCID 10898 | — |
| 반응물 | 5-(Tetradecyloxy)-2-furoic acid | HCID 115175 | — |
| 용매 | Ethyl Acetate | HCID 8857 | — |
| 생성물 | 2-Bromoethyl 5-(tetradecyloxy)furan-2-carboxylate | HCID 49869899 | — |
반응 단계
The title compound was prepared as described in Example 1 starting from 0.228 g (0.7 mmol) of 5-(tetradecyloxy)furan-2-carboxylic acid and 0.150 mL (2.1 mmol) of 2-bromoethanol. MS (m/z, ES+): 446.30 (79BrM+1, 100%), 448.30 (81BrM+1, 80%); 1H NMR (400 MHz, DMSO-d6) δ: 7.30 (d, 1H), 5.67 (d, 1H), 4.49 (t, 2H), 4.16 (t, 2H), 3.73 (t, 2H), 1.72 (p, 2H), 1.3-1.45 (m, 2H), 1.25 (s, 20H), 0.85 (t, 3H); EA found for C21H35BrO4: C, 58.93; H, 8.52; calcd: C, 58.47; H, 8.18.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09434718B2 |
| 출처 데이터셋 | uspto-grants-2016_09 |
| ORD ID | ord-7a14fb15a4214fa091f42d718bd63ae2 |
| 출처 메모 | uspto-grants-2016_09 |