2-Iodobenzylic alcohol → 2-Iodobenzaldehyde
반응식
[I:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH2:4][OH:5]>ClCCl.[O-2].[Mn+2]>[I:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH:4]=[O:5]참가 물질
4
실험 절차
In a flask, 2-iodobenzyl alcohol (4 g, 17.09 mmol) was dissolved in dichloromethane (MC, 85 ml), and then, manganese oxide (MnO2, 14.86 g, 170.92 mmol) was added thereto. The obtained reaction product was stirred under the reflux condition. When the reaction was completed, the obtained reaction product was cooled to the room temperature, and then, fiteated and concentrated using celite, to obtain the title compound (3.6 g, yield 91%).
후처리
- customThe obtained reaction product
- customthe obtained reaction product
- concentrationfiteated and concentrated
출처 및 근거
- ORD 기록
- ord-4e7787d867b241b6965a32d5b6f0e10d
- 출처 데이터셋
- uspto-grants-2015_05
- 특허 번호
- US09029589B2
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