2-Iodobenzylic alcohol → 2-Iodobenzaldehyde

HRID 573469

반응식

HRID 573469 반응식
[I:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH2:4][OH:5]>ClCCl.[O-2].[Mn+2]>[I:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH:4]=[O:5]

참가 물질

4

반응물 1

HCID 1076292-Iodobenzylic alcohol

생성물 1

HCID 6434392-Iodobenzaldehyde수율 91%

시약·촉매·용매 2

HCID 160959Manganese oxide촉매HCID 6344Dichloromethane용매

실험 절차

In a flask, 2-iodobenzyl alcohol (4 g, 17.09 mmol) was dissolved in dichloromethane (MC, 85 ml), and then, manganese oxide (MnO2, 14.86 g, 170.92 mmol) was added thereto. The obtained reaction product was stirred under the reflux condition. When the reaction was completed, the obtained reaction product was cooled to the room temperature, and then, fiteated and concentrated using celite, to obtain the title compound (3.6 g, yield 91%).

후처리

  1. customThe obtained reaction product
  2. customthe obtained reaction product
  3. concentrationfiteated and concentrated

출처 및 근거

ORD 기록
ord-4e7787d867b241b6965a32d5b6f0e10d
출처 데이터셋
uspto-grants-2015_05
특허 번호
US09029589B2

연결된 노트

불러오는 중…