Thionyl Chloride → Benzylthiocarbonyl chloride

HRID 581606

반응식

[C:1]1([CH2:7][C:8](O)=[S:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(Cl)([Cl:13])=O>>[C:1]1([CH2:7][C:8]([Cl:13])=[S:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

반응물 2

HCID 24386Thionyl Chloride

HCID 178526157HCID 178526157, 화합물

생성물 1

HCID 19906501Benzylthiocarbonyl chloride수율 92%

반응 조건

온도: 40 °C

실험 절차

A quantity of 762 g (4.536 mol) of 2-phenylthioacetic acid is stirred at room temperature for 3 hours with thionyl chloride (375 ml, 5.14 mol), then stirred at 40° C. for 3 hours. Rotary evaporation followed by bulb-to-bulb distillation gives 777 g (4.166 mol, 92%) of 2-phenylthioacetyl chloride.

후처리

customRotary evaporation
distillationfollowed by bulb-to-bulb distillation

출처 및 근거

ORD 기록: ord-e2aa14c9ba0f46cdbde657d3be99be68
출처 데이터셋: uspto-grants-1999_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05919951

연결된 노트

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