Water → 3-(Oxiran-2-yl)propyl 2-methylprop-2-enoate

HRID 582443노트

반응식

HRID 582443 반응식
[C:1]([O:6][CH2:7][CH2:8][CH2:9][CH:10]=[CH2:11])(=[O:5])[C:2]([CH3:4])=[CH2:3].C1C=C(Cl)C=C(C(OO)=[O:20])C=1.O>C(Cl)Cl>[C:1]([O:6][CH2:7][CH2:8][CH2:9][CH:10]1[O:20][CH2:11]1)(=[O:5])[C:2]([CH3:4])=[CH2:3]

참가 물질

5

반응물 3

HCID 962WaterHCID 70297m-Chloroperbenzoic acidHCID 20163830HCID 20163830, 화합물

생성물 1

HCID 220966403-(Oxiran-2-yl)propyl 2-methylprop-2-enoate

시약·촉매·용매 1

HCID 6344Dichloromethane용매2회

실험 절차

A solution of 4-pentenyl methacrylate (9 g) in methylene dichloride (15 ml) was added to a solution of m-CPBA (18 g) in methylene dichloride (150 ml) and the reaction was allowed to proceed for 5 hr. The reaction mixture was then poured into water, the organic phase was separated and then washed several times with a dilute solution of potassium carbonate. The reaction product was washed with water and then dried with anhydrous magnesium sulfate. A pure product was isolated by column chromatography on silica gel. Yield 7 g.

후처리

  1. customthe organic phase was separated
  2. washwashed several times with a dilute solution of potassium carbonate
  3. washThe reaction product was washed with water
  4. dry with materialdried with anhydrous magnesium sulfate
  5. customA pure product was isolated by column chromatography on silica gel

출처 및 근거

ORD 기록
ord-9618e77e2a0c4193bad9f502a3f091f1
출처 데이터셋
uspto-grants-1999_07
특허 번호
US05925253

반응 노트

불러오는 중…