참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Azobisisobutyronitrile | HCID 6547 | — |
| 반응물 | Benzyl methacrylate | HCID 17236 | — |
| 반응물 | Methyl 3-mercaptopropionate | HCID 18050 | — |
| 반응물 | 2-Methyldecane | HCID 23415 | — |
| 반응물 | 2-Butoxyethyl methacrylate | HCID 83555 | — |
| 반응물 | 2,2'-Azobis(2-cyclopropylpropionitrile) | HCID 21225683 | — |
| 생성물 | 3,6-Dimethyl-3-octanol | HCID 9027 | — |
반응 단계
A mixed solution of 16 g of Dispersion Stabilizing Resin (Q-1) having the structure shown below and 550 g of Isopar H was heated to a temperature of 50° C. under nitrogen gas stream while stirring. To the solution was dropwise added a mixed solution of 50 g of benzyl methacrylate, 40 g of 2-butoxyethyl methacrylate, 10 g Monomer (a-1) having the structure shown below, 2.6 g of methyl 3-mercaptopropionate and 1.2 g of 2,2'-azobis-(2-cyclopropylpropionitrile) (abbreviated as ACPP) over a period of one hour, followed by stirring for one hour. To the reaction mixture was added 0.8 g of ACPP, followed by reacting for 2 hours. Further, 0.5 g of 2,2'-azobis-(isobutyronitrile) (abbreviated as AIBN) was added thereto, the reaction temperature was adjusted to 80° C., and the reaction was continued for 3 hours. After cooling, the reaction mixture was passed through a nylon cloth of 200 mesh to obtain a white dispersion which was a latex of good monodispersity with a polymerization rate of 97% and an average grain diameter of 0.19 μm. The grain diameter was measured by CAPA-500 manufactured by Horiba Ltd. (hereinafter the same).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05928823 |
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| 출처 데이터셋 | uspto-grants-1999_07 |
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| ORD ID | ord-23b5817cae144c8b9561b0b4a310b48c |
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| 출처 메모 | uspto-grants-1999_07 |
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