HCID 70052140, 화합물 → HCID 21310855, 화합물

HRID 583328노트

반응식

HRID 583328 반응식
C[O:2][C:3](=[O:32])[C:4]1[CH:9]=[C:8]([CH3:10])[CH:7]=[C:6]([CH3:11])[C:5]=1[N:12]([CH2:24][C:25]1[CH:30]=[CH:29][CH:28]=[C:27]([Br:31])[CH:26]=1)[S:13]([C:16]1[CH:21]=[CH:20][C:19]([O:22][CH3:23])=[CH:18][CH:17]=1)(=[O:15])=[O:14]>CCOCC>[Br:31][C:27]1[CH:26]=[C:25]([CH:30]=[CH:29][CH:28]=1)[CH2:24][N:12]([S:13]([C:16]1[CH:21]=[CH:20][C:19]([O:22][CH3:23])=[CH:18][CH:17]=1)(=[O:15])=[O:14])[C:5]1[C:6]([CH3:11])=[CH:7][C:8]([CH3:10])=[CH:9][C:4]=1[C:3]([OH:32])=[O:2]

참가 물질

3

반응물 1

HCID 70052140HCID 70052140, 화합물

생성물 1

HCID 21310855HCID 21310855, 화합물수율 70.1%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

In the same manner as described in Example 109, 0.894 g (1.725 mmol) of the product of Example 107 provided 0.61 g (70%) of the desired carboxylic acid after trituration with ether. Electrospray Mass Spec 506.0 (M+H).

출처 및 근거

ORD 기록
ord-79570e95fb9f4d46b0c7ea8ba1a8d101
출처 데이터셋
uspto-grants-1999_07
특허 번호
US05929097

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