Epichlorohydrin → HCID 18980716, 화합물

HRID 583611노트

반응식

HRID 583611 반응식
[OH:1][CH:2]([CH2:17][N:18]([CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH3:47])[CH2:19][CH:20]([OH:35])[CH2:21][NH:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:3][NH:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[CH2:48]([CH:50]1[O:52][CH2:51]1)[Cl:49]>C1(C)C(C)=CC=CC=1>[OH:35][CH:20]([CH2:19][N:18]([CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH3:47])[CH2:17][CH:2]([OH:1])[CH2:3][N:4]([CH2:51][CH:50]([OH:52])[CH2:48][Cl:49])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:21][N:22]([CH2:51][CH:50]([OH:52])[CH2:48][Cl:49])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]

참가 물질

4

반응물 2

HCID 7835EpichlorohydrinHCID 18980712HCID 18980712, 화합물

생성물 1

HCID 18980716HCID 18980716, 화합물수율 99.4%

시약·촉매·용매 1

HCID 7237O-Xylene용매

실험 절차

A reactor was charged with 16.6 g (0.025 mole) of 15,19-dihydroxy-17-dodecyl-13,17,21-triazatritriacontane obtained in Example 1 and 200 g of xylene, and the contents were kept at 50° C. To the contents, 6.9 g (0.075 mole) of epichlorohydrin was added dropwise over one hour and ten minutes, and the resultant mixture was aged for 36 hours. Thereafter, the solvent and unreacted epichlorohydrin were distilled off under reduced pressure at room temperature, thereby obtaining 21.2 g of 15,19-dihydroxy-13,21-bis(3-chloro-2-hydroxypropyl)-17-dodecyl-13,17,21-triazatritriacontane represented by the following formula. ##STR14##

후처리

  1. customwere kept at 50° C
  2. distillationThereafter, the solvent and unreacted epichlorohydrin were distilled off under reduced pressure at room temperature

출처 및 근거

ORD 기록
ord-33d8121217384a17b1cc8a3958544b46
출처 데이터셋
uspto-grants-1999_07
특허 번호
US05929283

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