1-vinylcyclooctanol → HCID 54012738, 화합물

HRID 583642노트

반응식

HRID 583642 반응식
[CH:1]([C:3]1(O)[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4]1)=[CH2:2]>C1C=CC=CC=1>[CH:1]([C:3]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH:4]=1)=[CH2:2]

참가 물질

3

반응물 1

HCID 35315111-vinylcyclooctanol

생성물 1

HCID 54012738HCID 54012738, 화합물수율 67%

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

A solution of 6 grams of 1-vinylcyclooctanol and 50 mg of MTO in 30 ml of benzene was refluxed 18 hours, cooled, washed with aq. potassium carbonate, dried, stripped of solvent and distilled (82-85 deg C./25 mm Hg) to give 3.55 grams of 1-vinylcyclooctene judged to be of 95% purity of NMR analysis; the only impurity was cyclooctanone left over from preparation of the vinyl carbinol.

후처리

  1. temperaturecooled
  2. washwashed with aq. potassium carbonate
  3. customdried
  4. distillationdistilled (82-85 deg C./25 mm Hg)

출처 및 근거

ORD 기록
ord-70daa4ab3cf944569c513bad25c84f94
출처 데이터셋
uspto-grants-1999_07
특허 번호
US05929298

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