HCID 86595798, 화합물 → HCID 86595804, 화합물

HRID 586660노트

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HRID 586660 반응식
COC[C@@H]1[C@H](C=O)[C@]1(C)C1C=CC2C(C)(C)CCC(C)(C)C=2C=1.CC12C(C)(C)[C:28]([C:34]([O:36][CH2:37][C@H:38]3[C@H:40]([CH2:41][O:42]CC)[C@@:39]3([CH3:59])[C:45]3[CH:54]=[CH:53][C:52]4[C:51]([CH3:56])([CH3:55])[CH2:50][CH2:49][C:48]([CH3:58])([CH3:57])[C:47]=4[CH:46]=3)=O)(CC1)OC2=O>>[CH2:34]([O:36][CH2:37][C@H:38]1[C@H:40]([CH:41]=[O:42])[C@:39]1([CH3:59])[C:45]1[CH:54]=[CH:53][C:52]2[C:51]([CH3:56])([CH3:55])[CH2:50][CH2:49][C:48]([CH3:58])([CH3:57])[C:47]=2[CH:46]=1)[CH3:28]

참가 물질

3

반응물 2

HCID 86595798HCID 86595798, 화합물HCID 86595801HCID 86595801, 화합물

생성물 1

HCID 86595804HCID 86595804, 화합물수율 98%

실험 절차

Following a procedure similar to that for the preparation of Intermediate 12a but using Intermediate 10b as the starting material afforded the title compound (27 mg, 98% yield) as a colorless oil:

출처 및 근거

ORD 기록
ord-ca631caa00d145cd93d781f826520b38
출처 데이터셋
uspto-grants-2005_08
특허 번호
US06936636B2

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