참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Ethanol | HCID 702 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | Chlorosulfonic acid | HCID 24638 | — |
| 반응물 | Tricyclohexylbenzene | HCID 3015433 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Sodium 1,3,5-tricyclohexylbenzenesulfonate | HCID 86655172 | — |
반응 단계
Tricyclohexylbenzene amounting to 30 g was dissolved in 50 ml of methylene chloride and agitated while cooling at 3° C. Then, 15.2 g of chlorosulfonic acid was slowly dropped into the solution. After the completion of the dropping, the mixture was agitated at room temperature for five hours. Subsequently, 10 g of ice and then 40 g of 50% aqueous sodium hydroxide solution was poured into the mixture. Further, 20 g of ethanol was added and agitated at 50° C. for an hour. Any insoluble matter was removed by filtration, and the product was subjected to vacuum distillation at 40° C. The thus obtained crystal was collected by filtration, and washed with hexane, thereby obtaining 30 g of sodium 1,3,5-tricyclohexylbenzenesulfonate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US09235116B2 |
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| 출처 데이터셋 | uspto-grants-2016_01 |
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| ORD ID | ord-43f04fccdfa146fda9f1cee1f1fec542 |
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| 출처 메모 | uspto-grants-2016_01 |
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