참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Chlorobutanol | HCID 5977 | — |
| 반응물 | Methyl 2-chloro-2-methylpropanoate | HCID 211144 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | Methacrylic Acid | HCID 4093 | — |
| 생성물 | Methyl Methacrylate | HCID 6658 | — |
| 생성물 | (1,1,1-Trichloro-2-methyl-2-propyl) methacrylate | HCID 118163057 | — |
| 생성물 | (1,1,1-Trichloro-2-methyl-2-propyl) 2-chloro-2-methylpropanoate | HCID 118163068 | — |
반응 단계
To 2.83 g of the crude reaction solution obtained was added 0.11 g of methanol, followed by heating at 60° C. for 4 hours. Then, it was found out by gas chromatography analysis that the conversion of the 1,1,1-trichloro-2-methyl-2-propanol was 86.0% and the yield of methyl 2-chloro-2-methylpropanoate was 10.2%. As to other products, it was obtained methyl methacrylate in a 0.2% yield, methacrylic acid in a 8.7% yield, (1,1,1-trichloro-2-methyl-2-propyl) methacrylate in a 13.1% yield, and (1,1,1-trichloro-2-methyl-2-propyl) 2-chloro-2-methylpropanoate in a 22.8% yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09238612B2 |
|---|
| 출처 데이터셋 | uspto-grants-2016_01 |
|---|
| ORD ID | ord-77e6c5fd78e34424b45ba1d920c490c3 |
|---|
| 출처 메모 | uspto-grants-2016_01 |
|---|
