L-Glutamic acid, 5-(phenylmethyl) ester → L-Glutamic Acid

HRID 595531

반응식

HRID 595531 반응식
[NH2:1][C@H:2]([C:18]([OH:20])=[O:19])[CH2:3][CH2:4][CH2:5][CH2:6][NH:7][C:8]([O:10][CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[O:9].[NH2:21][C@H:22]([C:35]([OH:37])=[O:36])[CH2:23][CH2:24][C:25](=[O:34])[O:26]CC1C=CC=CC=1>>[NH2:21][C@H:22]([C:35]([OH:37])=[O:36])[CH2:23][CH2:24][C:25](=[O:26])[OH:34].[CH:15]1[CH:16]=[CH:17][C:12]([CH2:11][O:10][C:8]([NH:7][CH2:6][CH2:5][CH2:4][CH2:3][CH:2]2[NH:1][C:25](=[O:26])[O:20][C:18]2=[O:19])=[O:9])=[CH:13][CH:14]=1

참가 물질

4

반응물 2

HCID 122337L-Glutamic acid, 5-(phenylmethyl) esterHCID 1715626epsilon-(Benzyloxycarbonyl)-L-lysine

생성물 2

HCID 33032L-Glutamic AcidHCID 15927786Benzyl [4-(2,5-dioxo-1,3-oxazolidin-4-yl)butyl]carbamate

실험 절차

H-Lys(Z)—OH and H-Glu(OBn)-OH were purchased from Chem-Impex International (Des Plaines, Ill.) and used as received. Glu-NCA and Lys-NCA were prepared by following previously reported procedures (Lu, H.; Cheng, J. J. Am. Chem. Soc. 2007, 129, 14114-14115).

출처 및 근거

ORD 기록
ord-78fa33bf4e744c9492bba467fa00a200
출처 데이터셋
uspto-grants-2016_01
특허 번호
US09243040B2

연결된 노트

불러오는 중…