Isoprene → Isoprene acrylonitrile

HRID 595617

반응식

[CH2:1]=[CH:2][C:3](=[CH2:5])[CH3:4].Cl[CH:7]([CH3:10])[C:8]#[N:9]>>[CH2:1]=[CH:2][C:3](=[CH2:4])[CH3:5].[C:8](#[N:9])[CH:7]=[CH2:10]

참가 물질

반응물 2

HCID 6557Isoprene

HCID 5192252-Chloropropionitrile

생성물 1

HCID 168239Isoprene acrylonitrile

반응 조건

온도: 80 °C

실험 절차

Then, were added thereto 68.2 parts of isoprene and 1.79 parts of 2-chloropropionitrile as an organic halide and stirred under heating at 80° C. to conduct a polymerization reaction. After 137 hours, the same post-treatment as in Example 1 was carried out to give a random (isoprene/acrylonitrile) copolymer. The conversion rate of isoprene was 84% and the conversion rate of acrylonitrile was 79%. The analysis results of the random (isoprene/acrylonitrile) polymer obtained are shown in Table 3. The polymer was confirmed to have a chlorine atom at the terminal of the polymer chain.

후처리

additionThen, were added
customa polymerization reaction

출처 및 근거

ORD 기록: ord-60e0a25855b74722ac70ab07752689e7
출처 데이터셋: uspto-grants-2016_01
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09243100B2

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