Trifluoroacetic acid → 3(2H)-Benzofuranone, 2-(methylthio)-
반응식
[OH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8](=[O:13])[CH2:9][S:10]([CH3:12])=O.FC(F)(F)C(O)=O>C1C=CC=CC=1>[CH3:12][S:10][CH:9]1[C:8](=[O:13])[C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[O:1]1참가 물질
4
실험 절차
2-Hydroxy-1-[(methylsulfinyl) acetyl]benzene (1.5 g 0.0075m) and trifluoroacetic acid (1.5 g) are refluxed in benzene (25 ml) for one hour under nitrogen. The solvent is removed under reduced pressure to give a pale yellow oil which crystallizes on standing. Recrystallization from ethanol gave white crystals, (0.611 g 45%), m.p. 81°-82° C.
후처리
- customThe solvent is removed under reduced pressure
- customto give a pale yellow oil which
- customcrystallizes
- customRecrystallization from ethanol
- customgave white crystals, (0.611 g 45%), m.p. 81°-82° C.
출처 및 근거
- ORD 기록
- ord-7fd3f2e8b2a947d2b73a4b6e5bcb88db
- 출처 데이터셋
- uspto-grants-1977_03
- 특허 번호
- US04012422
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